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General derivations of the equipartition theorem can be found in many statistical mechanics textbooks, both for the microcanonical ensemble and for the canonical ensemble. They involve taking averages over the phase space of the system…
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In chemistry, an ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding.
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In the presence of an electrostatic field there is Stark splitting which allows molecular electric dipole moments to be determined.